Two-dimensional NMR spectroscopy

Definition

The heteronuclear correlation of chemical shifts by scalar coupling derives from the existence of heteronuclear scalar coupling all owing a magnetization transfer from the more sensitive nucleus toward the less sensitive nucleus .

The model experiment is the correlation which uses the large direct coupling comprised between more 100 Hz and 200Hz and which allows to correlate the signals from a proton to that of a to which it is bound[1].

  1. BRUKER

    RMN 2D. 1993 Poly. 1 2 et 3.

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