The 2D NMR - The idea of JEENER
The idea of Jeener consists in the stepwise increasing of the evolution time .
This will allow to get an NMR signal under the aspect of a sampling of free precession signals of the type. These FID will differ from each other only by the period duration written under a matricial form
s( , ). The delay is the time between the first and the second pulse.
The first Fourier transform as a function of gives us an interferogram of the form (Fig. 10)
A second Fourier transform, versus the second variable , gives an NMR spectrum with two frequencies dimensions F1 and F2.
The result of this two fold Fourier transform does not get two spectra and but only one spectrum as a function of two independent frequencies, exhibiting a peak with the coordinates . Thus, an aimantation evolving with the frequency in the time course has been converted in another coherence evolving with the frequency during the period .
This double Fourier transform in both dimension yields thus a matrix (spectrum 3).